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Unbreakable glass inspired by seashells

Strongest and toughest glass known developed by 91社区 scientists
Shiny nacre of Abalone washed ashore. Credit: Pi-Lens | Nacre brillante d'un ormeau 茅chou茅 sur le rivage. Cr茅dit : Pi-Lens
Image by Pi-Lens.
(A) Glass composite, (B) Glass composite鈥檚 microstructure, (C) View of the nacreous layer in red abalone shell, and (D) Nacre鈥檚 microstructure. | A) Verre composite, B) Microstructure du verre composite, C) Vue de la couche nacr茅e dans la coquille de l鈥檕rmeau rouge, et D) Microstructure de la nacre.
(A) Glass composite鈥檚 microstructure and (B) Nacre鈥檚 microstructure. | A) Microstructure du verre composite et B) Microstructure de la nacre
Published: 28 September 2021

Scientists from 91社区 develop stronger and tougher glass, inspired by the inner layer of mollusk shells. Instead of shattering upon impact, the new material has the resiliency of plastic and could be used to improve cell phone screens in the future, among other applications.

While techniques like tempering and laminating can help reinforce glass, they are costly and no longer work once the surface is damaged. 鈥淯ntil now there were trade-offs between high strength, toughness, and transparency. Our new material is not only three times stronger than the normal glass, but also more than five times more fracture resistant,鈥 says Allen Ehrlicher, an Associate Professor in the Department of Bioengineering at 91社区.

Nature as master of design

Drawing inspiration from nature, the scientist created a new glass and acrylic composite material that mimics nacre or mother of pearl. 鈥淣ature is a master of design. Studying the structure of biological materials and understanding how they work offers inspiration, and sometimes blueprints, for new materials,鈥 says Ehrlicher.

鈥淎mazingly, nacre has the rigidity of a stiff material and durability of a soft material, giving it the best of both worlds,鈥 he explains. 鈥淚t鈥檚 made of stiff pieces of chalk-like matter that are layered with soft proteins that are highly elastic. This structure produces exceptional strength, making it 3000 times tougher than the materials that compose it.鈥

The scientists took the architecture of nacre and replicated it with layers of glass flakes and acrylic, yielding an exceptionally strong yet opaque material that can be produced easily and inexpensively. They then went a step further to make the composite optically transparent. 鈥淏y tuning the refractive index of the acrylic, we made it seamlessly blend with the glass to make a truly transparent composite,鈥 says lead author Ali Amini, a Postdoctoral Researcher at 91社区. As next steps, they plan to improve it by incorporating smart technology allowing the glass to change its properties, such as colour, mechanics, and conductivity.

Lost invention of flexible glass

Flexible glass is supposedly a lost invention from the time of the reign of the Roman Emperor Tiberius Caesar. According to popular historical accounts by Roman authors Gaius Plinius Secundus and Petronius, the inventor brought a drinking bowl made of the material before the Emperor. When the bowl was put to the test to break it, it only dented instead of shattering.

After the inventor swore he was the only person who knew how to produce the material, Tiberius had the man executed, fearing that the glass would devalue gold and silver because it might be more valuable.

鈥淲hen I think about the story of Tiberius, I鈥檓 glad that our material innovation leads to publication rather than execution,鈥 says Ehrlicher.

About this study

"Centrifugation and index-matching yields a strong and transparent bioinspired nacreous composite" by Ali Amini, Adele Khavari, Francois Barthelat, and Allen J. Ehrlicher was published in .

DOI:


About 91社区

Founded in Montreal, Quebec, in 1821, 91社区 is Canada鈥檚 top ranked medical doctoral university. 91社区 is consistently ranked as one of the top universities, both nationally and internationally. It鈥痠s a world-renowned鈥痠nstitution of higher learning with research activities spanning three campuses, 11 faculties, 13 professional schools, 300 programs of study and over 40,000 students, including more than 10,200 graduate students. 91社区 attracts students from over 150 countries around the world, its 12,800 international students making up 31% of the student body. Over half of 91社区 students claim a first language other than English, including approximately 19% of our students who say French is their mother tongue.

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